Liquid-Liquid InterfacesTheory and Methods

'Liquid-Liquid Interfaces Theory and Methods' presents contemporary reviews by world leaders in research related to electrochemical, biological and photochemical effects in interfacial phenomena.

Update your knowledge of the chemical, biological, and physical properties of liquid-liquid interfaces with Liquid-Liquid Interfaces: Theory and Methods. This valuable reference presents a broadly based account of current research in liquid-liquid interfaces and is ideal for researchers, teachers, and students. Internationally recognized investigators of electrochemical, biological, and photochemical effects in interfacial phenomena share their own research results and extensively review the results of others working in their area. Because of its unusually wide breadth, this book has something for everyone interested in liquid-liquid interfaces. Topics include interfacial and phase transfer catalysis, electrochemistry and colloidal chemistry, ion and electron transport processes, molecular dynamics, electroanalysis, liquid membranes, emulsions, pharmacology, and artificial photosynthesis. Enlightening discussions explore biotechnological applications, such as drug delivery, separation and purification of nuclear waste, catalysis, mineral extraction processes, and the manufacturing of biosensors and ion-selective electrodes.Liquid-Liquid Interfaces: Theory and Methods is a well-written, informative, one-stop resource that will save you time and energy in your search for the latest information on liquid-liquid interfaces.

Equilibrium Electric Potential Between Two Immiscible Electrolyte Solutions, T. KakiuchiDistribution PotentialPolarizability of the Liquid-Liquid InterfaceNonpolarized ITIES and Reference Potentials in Organic PhasesFree Energy of Coupling of Ion Transfer and Electron TransferConclusionsReferencesVolta and Surface Potentials at Liquid/Liquid Interfaces, Z. KoczorowskiIntroductionElectrified Liquid-Liquid Interfaces and Their Electrical PotentialsVolta Potential and Voltaic CellsVoltaic Cells with Water/Nonpolar Liquid InterfacesVoltaic Cells with Immiscible Electrolyte Solution InterfaceExperimental Methods of Investigation of Voltaic CellsFinal RemarksReferencesIon Solvation, Y. MarcusIntroductionThe Relevant Properties of IonsThe Relevant Properties of SolventsQuantities Describing Ionic HydrationTransfer of Ions into Non-Aqueous SolventsPreferential Ion Solvation in Mixed SolventsReferencesAdsorption Isotherms and the Structure of Oil/Water Interface, V.S. Markin and A.G. VolkovIntroductionSurface Solution ModelAnalysis of the Generalized Frumkin IsothermClassical Isotherms as a Special Case of the Generalized Adsorption IsothermAdsorption Isotherm and the Structure of InterphaseConclusionReferencesThe Electrical Double Layer at Liquid-Liquid Interfaces, A. Watts and T.J. VanderNootIntroductionModels of Electrolytes and Double LayersSimulations of Solvents and InterfacesExperimental MethodsConclusionsReferencesSecond Harmonic Generation at Liquid-Liquid Interfaces, P.F. Brevet and H.H. GiraultIntroductionHistorical OverviewTheoryExperimental ApparatusSurface SH Origin from Neat Liquid-Liquid InterfacesMolecular Orientation at Liquid-Liquid InterfacesInterfacial Chemical EquilibriumDynamics at Liquid-Liquid InterfacesSurface Sum-Frequency GenerationConclusionReferencesQuantum Theory of Charge Transfer, Y.I. Kharkats and A.M. KuznetsovPhysical Mechanism of Charge Transfer and the Role of Polar MediumOuter-Sphere Solvent Reorganization EnergyElectron Transfer at the Interface and Specific Forms of the Solvent Reorganization EnergyIon Transfer Across the Interface of Two PhasesReferencesKinetics of Charge Transfer, Z. SamecIntroductionIon TransferElectron TransferReferencesMolecular Dynamics of Charge Transfer at the Liquid-Liquid Interface, I. BenjaminIntroductionThe Neat InterfaceElectron TransferIon TransferConclusions and OutlookReferencesPhotoelectrochemical Effect at Interface Between Two Immiscible Electrolytic Solutions, N.A. Kotov and M.G. KuzminIntroductionReactions of Charge Transfer at Liquid-Liquid Interfaces in Microheterogeneous SystemsPhotoelectrochemical Effect at the Interface of Immiscible Electrolyte SolutionsConclusionReferencesExcited State Electron Transfer at the Interface of Two Immiscible Electrolyte Solutions, M.K. De Armond and A.H. De ArmondIntroductionElectrochemical Probing of the ITIESElectron Transfer KineticsTheory of Electron Transfer Rates Across Liquid-Liquid Interfaces (from Marcus and Benjamin)The Photochemical Redox ProcessPhotoeffects at the Polarized Liquid-Liquid InterfaceAnomalous PhotoeffectsKinetics of Charge TransferThe Instrumental SystemChemicalsThe Future of ITIES PhotoeffectsReferencesAmperometric Ion-Selective Electrode Sensors, M. Senda and Y. YamamotoIntroductionElectrochemical Principle of Ion-Selective Electrode (ISE)Amperometric ISE SensorsAmperometric ISE BiosensorsElectroanalytical Chemistry at Liquid-Liquid InterfacesReferencesImmiscible Liquid Interface and Self-Organized Assemblies of Lecithin,Y.A. ShchipunovIntroductionLecithin Self-Assembly and Self-Organization at the InterfaceInterfacial Structures and Ternary Phase DiagramsElectrointerfacial PhenomenaMethodsProspects for Applications and Further StudiesReferencesPhospholipid Monolayers and Phospholipases, T. KakiuchiProperties of Phospholipid Monolayers at ITIESCharge Transfer Across the Phospholipid Monolayer at ITIESInterfacial Enzymatic Reactions at ITIESReferencesElectrodialysis Through Liquid Ion-Exchange Membranes and Oil/Water Interface, A.N. PopovIntroductionRegularities of Electrodialysis Through Liquid MembranesApplication of Electrodialysis of Liquid MembranesExperimental ApparatusConclusion ReferencesOil/Water Interfaces and the Origin of Life, D.W. Deamer and A.G. VolkovLiquid-Liquid Interfaces and Chemical Evolution on the Early EarthEnvironmental Conditions of the Prebiotic EarthSources of Prebiotic Organic CompoundsMembranes and Liquid-Liquid InterfacesPhotochemistry in the Prebiotic Environment: Synthesis of AmphiphilesProton Production by PAH in HydrocarbonCarbon Dioxide Reactivity in PAH-Alkane SystemsConclusionsReferencesElectrochemical Behavior of Drugs at the Oil/Water Interface, K. Arai, F. Kusu, and K. TakamuraIntroductionIon-Transfer Voltammetry at the Oil/Water InterfaceElectrical Potential Oscillation Across a Liquid MembraneConclusionReferencesElectrocatalysis and Electrolysis, V.J. Cunnane and L. MurtomäkiIntroductionTheory of Two Phase Electron Transfer ReactionsModel SystemsElectrocatalysis and ElectrodepositionSummary and Future DevelopmentsReferencesSubject Index

Volkov\, Alexander G.; Deamer\, David W.